Chapter wise questions on "Coordination Compounds" is provided below.
81) Which is a double salt?
a) $ K_{2}SO_{4}.Al_{2}(SO_{4})_{3}.24H_{2}O $
b) $ NaCl $
c) $ K_{4}[Fe(CN)_{6}] $
d) $ KCl $
82) An example of a complex compound having co-ordination number 4.
a) $ K_{4}[Fe(CN)_{6}] $
b) $ [Co(en)_{3}]Cl_{3} $
c) $ [Fe(H_{2}O)_{6}]Cl_{3} $
d) $ [Cu(NH_{3})_{4}]Cl_{2} $
83) The geometry of $ [Cu(NH_{3})_{4}]^{2+} $ complex ion:
a) Linear
b) Tetrahedral
c) Square planar
d) Angular
84) An example of chelating ligand is:
a) $ NO_{2}^{-} $
b) Chloro
c) Bromo
d) en
85) The geometry of complex ion $ [Fe(CN)_{6}]^{4-} $ is:
a) tetrahedral
b) square plannar
c) Octahedral
d) triangular
86) The oxidation number of Nickel in the complex ion, $ [NiCl_{4}]^{2-} $ is:
a) +1
b) –1
c) +2
d) –2
87) Which is not an anionic complex:
a) $ [Cu(NH_{3})_{4}]Cl_{2} $
b) $ K_{4}[Fe(CN)_{6}] $
c) $ K_{3}[Fe(CN)_{6}] $
d) $ [NiCl_{4}]^{2-} $
88) The geometry of $ [Ni(CN)_{4}]^{2-} $ is:
a) Tetrahedral
b) Square planar
c) Triangular
d) Octahedral
89) An example of an ambidentate ligand is:
a) $ CN^{-} $
b) $ Cl^{-} $
c) $ NO_{2}^{-} $
d) $ I^{-} $
90) $ [FeF_{6}]^{4-} $ is a para-magnetic because:
a) $ F^{-} $ is a weaker ligand
b) $ F^{-} $ is a strong ligand
c) $ F^{-} $ is a flexidentate ligand
d) $ F^{-} $ is a chelating ligand
91) In $ [Fe^{11}(CN)_{6}]^{4-} $, the central metal ion is:
a) Fe
b) $ Fe^{+2} $
c) $ Fe^{+3} $
d) $ CN^{-} $
92) The co-ordination number of Ni(H) in $ [Ni(CN)_{4}]^{2-} $ is:
a) 2
b) 4
c) 5
d) 6
93) The name of $ [Pt^{IV}(NH_{3})_{2}Cl_{2}]^{2+} $ is:
a) Diamminedichloroplatinum(IV) ion
b) Diamminedichloroplanitate(IV)
c) Diamminedichloroplatinum
d) Dichlorodiammineplatinum(IV) ion
94) For a comound $ K_{4}[Fe(CN)_{6}] \rightarrow 4K^{+} + [Fe(CN)_{6}]^{4-} $, the complex ion is:
a) $ K^{+} $
b) $ CN^{-} $
c) $ Fe^{II} $
d) $ [Fe(CN)_{6}]^{4-} $
95) A metal ion from the first transition series forms an octahedral complex with magnetic moment of 4.9 BM and another octahedral complex which is diamagnetic. The metal ion is:
a) $ Fe^{2+} $
b) $ Co^{2+} $
c) $ Mn^{2+} $
d) $ Ni^{2+} $
96) Paramagnetic moment is expressed in:
a) Debye unit
b) K Joules
c) BM
d) ergs
97) The type of isomerism found in the complexes $ [Co(NO_{2})(NH_{3})_{5}]SO_{4} $ and $ [Co(SO_{4})(NH_{3})_{5}]NO_{2} $ :
a) Hydrate isomerism
b) Coordination isomerism
c) Linkage isomerism
d) Ionisation
98) Valence bond theory does not explain the property of complex compound:
a) geometry
b) magnetic
c) nature of ligand
d) colour
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